Something sounds off there. I went almost the exact opposite with the hybrid cooler, ~100C on air, ~80C on the hybrid. With it being a 3090 though, I wonder if it made the VRAM on the front cooler, but then the back is running hotter?
Looking at the design though, I do feel like the VRM plate could be thicker copper. It's pretty thin, like 0.030" thick and then doesn't have a ton of contact with the AIO. Going to a thicker copper plate and then using thinner thermal pads could possibly improve the situation. Not completely sure there is room for a thicker plate though.
Also, not sure it matters, but the shroud doesn't really guide the air into the heat sinks, and the AIO blocks a lot of the flow path to the second heatsink. I've been thinking about 3D print a new shroud that makes it like a triple slot card with a standard 90mm fan.