Had this same behavior after I flashed the OC switch 450W bios. Turned my PC off, switched it back to Normal mode and it behaves normally, with the LED button reappearing.
The all red power LEDs and fans to 100% during flashing is normal behavior.
I would highly recommend, uninstall PX1, turn your PC off, switch to normal mode on the switch, reinstall latest PX1 ver 1.1.0.11. If LED button comes back, then turn off PC, switch back to OC mode, and check if your LED button reappears. This is what I had to do, now all is well.