PSU on is a good sign..I would put it all together and roll from there..Install the CPU and cooler, RAM, graphics card, HDD and all..Connect the System Panel/Front Panel Connector/Q-Connector making sure + and - polarity of things is right, and all the other connectors..You can do all that on a table if the board is out of the case.
What do you need the 4-pin PERIF cable for?..Connected to what?