In the Fan Control tab there is a drop down to the right of "Controlled speed". What is shown in that drop down? For me it is Pwm1 thru Pwm5, and each controls a fan header, but they are not named the same as what is printed on the motherboard. I tested each one to learn which header was being controlled. For me they are:
Pwm1 = CPU_FAN (controlled by Core 1 CPU temp)
Pwm2 = CPU_OPT (controlled by GPU temp)
Pwm3 = SYS_FAN2 (controlled by GPU temp)
Pwm4 = SYS_FAN3 (controlled by GPU temp)
Pwm5 = SYS_FAN1 (controlled by GPU temp)