Hello, my recommendation would be use your cards in 1 and 4 and the SSD in 3.
http://www.evga.com/support/manuals/files/152-HR-E979-Part1.pdf on page 9 of this PDF you can see the lane breakdown, these are in all current generation manuals.
This is true on any of your 4 way boards that use 16 lane CPUs; PCIE slot 1 is form the CPU, if ONLY that slot is used then you will have 16 lanes form the CPU to that slot. Now if you use any other x16 slot (meaning mechanical 16 not necessarily having that many lanes) 8 lanes are pulled from the CPU and provided to the PLX for replication. Now the PLX will provide 32 lanes, 16 to the second and 4th PCIE slot. Those will both be 16 unless you populate slots 3 or 6 which will divide the lanes available to 8 for slots 2 and 4 respectively.
TL;DR
I would do it like this:
PE1: GPU (8x)
PE2: Empty (8x form PLX)
PE3: SSD (8x form PLX)
PE4: GPU (16x from PLX)
PE5: Empty (1x from PCH)
PE6: Empty
SSD can go into 2 or 3 for the same performance, I went with 3 for better airflow if you are not water cooling.
I agree with the more lanes, Z chips imho should be 28, then X series chips should be 40 for baseline and 64 for extreme editions.